Qgis how to combine a geotif with a country border shape file?

I have 2 files. A geotif with different values and 1 shape file with country borders of this area. Can I generate with this 2 files an image with the country borders and the data from the geotif?

I'm also interested in any other software/scripting solution for this. I did the second Image with matplotlib and basemap but the country borders are wrong (outdated).